Orbital - Vol. 10 No. 6 - July-September 2018
FULL PAPERS

Solution Complexation Reaction Studies of a Pyrazoloisoindol Derivative Ligand by Some Metal Ions in Acetonitrile Solution

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  • Mahmood Payehghadr,
  • Hamidreza Haghgoo Qezelje,
  • Farzaneh Miri Dosangani,
  • Asghar Amiri,
  • Samaneh Hosseini,
  • Masoumeh Nabati Hesarlo,
  • Amirsajad Soleymani Kia
Mahmood Payehghadr
Department of Chemistry, Payame Noor University, Tehran, Iran
Hamidreza Haghgoo Qezelje
Department of Chemistry, Payame Noor University, Tehran, Iran
Farzaneh Miri Dosangani
Department of Chemistry, Payame Noor University
Asghar Amiri
Department of Chemistry, Payame Noor University
Samaneh Hosseini
Department of Chemistry, Payame Noor University
Masoumeh Nabati Hesarlo
Department of Chemistry, Payame Noor University, Tehran, Iran
Amirsajad Soleymani Kia
Department of Chemistry, Kashan University
Published September 9, 2018
Keywords
  • complexation,
  • spectrophotometry,
  • conductometry,
  • formation constant,
  • pyrazoloisoindol
How to Cite
(1)
Payehghadr, M.; Qezelje, H. H.; Dosangani, F. M.; Amiri, A.; Hosseini, S.; Hesarlo, M. N.; Kia, A. S. Solution Complexation Reaction Studies of a Pyrazoloisoindol Derivative Ligand by Some Metal Ions in Acetonitrile Solution. Orbital: Electron. J. Chem. 2018, 10, 430-434.

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Abstract

The complexation reaction between some heavy metal ions such as: Ag+, Co2+, Hg2+, Zn2+, Ni2+, Cu2+, Cd2+, Mn2+, Cr3+, Fe3+ and Pb2+ with 2,3-dimethyl-1,2-dihydro-8H-pyrazolo[5,1-a]isoindol-8-one, ligand in acetonitrile as nonaqueous solvents at 25 ºC were investigated by spectrophotometric and conductometric methods. The formation constants (kf) of the 1:1 (metal ion to ligand) complexes were calculated by computer fitting of the absorbance-mole ratio data, and molar conductance-mole ratio data at 25 ºC using the KINFIT program, and found that complexes to vary in acetonitrile solvent in the order of Zn2+> Ag+> Cr3+> Ni2+> Hg2+> Fe3+> Cu2+> Cd2+> Co2+> Mn2+> Pb2+.

DOI: http://dx.doi.org/10.17807/orbital.v10i6.1141

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