Orbital - Vol. 8 No. 2 - January-March 2016
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Modelagem Matemática da Solubilização dos Polímeros Condutores por Meio de Processos Polimeranalógicos

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  • Volodymyr Tkach,
  • Vasyl´ Nechyporuk,
  • Petro Ivanovych Yagodynets´,
  • Olena Aksimentyeva,
  • Ana S. M. Rodrigues Conde,
  • Aline M. da Rocha,
  • Reza Ojani
Volodymyr Tkach
Universidade Nacional de Chernivtsi
Vasyl´ Nechyporuk
Chernivtsi National University
Petro Ivanovych Yagodynets´
Chernivtsi National University
Olena Aksimentyeva
L´viv National University
Ana S. M. Rodrigues Conde
Universidade do Porto
Aline M. da Rocha
Universidade Federal de Minas Gerais
Reza Ojani
University of Mazandaran
Published April 4, 2016
Keywords
  • conducting polymers,
  • solubilization,
  • electrophilic substitution,
  • self-doping,
  • stable steady-state
How to Cite
(1)
Tkach, V.; Nechyporuk, V.; Yagodynets´P. I.; Aksimentyeva, O.; Conde, A. S. M. R.; da Rocha, A. M.; Ojani, R. Modelagem Matemática Da Solubilização Dos Polímeros Condutores Por Meio De Processos Polimeranalógicos. Orbital: Electron. J. Chem. 2016, 8, 102-107.

Copyright (c) 2016 Orbital: The Electronic Journal of Chemistry

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Abstract

The transition of conducting polymer from insoluble to the soluble state by chemical and electrochemical way, experimentally observed, gains its mathematical representation by means of the developed model, which was described and analyzed by means of linear stability theory and bifurcation analysis. It was shown that the influence on the behavior of the system may come not only of strongly acid media and the presence of surfactants, but also of electrophilic substitution and self-doping. Also, the behavior of the system has been compared by the electrosynthesis of conducting polymers, non-accompanied by solubilization.

DOI: http://dx.doi.org/10.17807/orbital.v8i2.621

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