SHORT COMMUNICATIONS
Preparação de um Sinton Funcionalizado a Partir da Carvona Visando a Síntese de alfa-metileno-gama-butirolactonas Monoterpênicas
Published
December 20, 2015
Keywords
- (R)-(-)-carvone,
- monoterpene,
- -methylene--butyrolactones,
- stereoselective synthesis
How to Cite
(1)
dos Santos, R. B.; César, R. C. V.; Lacerda Jr., V.; Greco, S. J.; Cunha Neto, A. Preparação De Um Sinton Funcionalizado a Partir Da Carvona Visando a Síntese De Alfa-Metileno-Gama-Butirolactonas Monoterpênicas. Orbital: Electron. J. Chem. 2015, 7, 395-400.
Copyright (c) 2015 Orbital: The Electronic Journal of Chemistry
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Abstract
(R)-(-)-Carvone (6) has been transformed into oxygenated derivative 13, which is expected to be a useful synthon or chiral template in the synthesis of natural a-methylene-g-butyrolactones. This synthesis of compound 13 involves classics reactions of oxygenation in saturated carbon with full control of regioselectivity and stereoselectivity.