Orbital - Vol. 12 No. 2 - April-June 2020
FULL PAPERS

The Theoretical Description of Cathodic Deposition of New Conducting Polymer Composite, Assisted by a Perrhenate of a Novel Triazolic Derivative

Volodymyr V. Tkach
Chernivtsi National University
Marta V. Kushnir
Chernivtsi National University
Nataliia M. Storoshchuk
Chernivsi National University
Volodymyr V. Parchenko
Zaporizhzhya National University
Ilona I. Aksyonova
Zaporizhzhya National University
Vira M. Odyntsova
Zaporizhzhya National University
Olga V. Luganska
Zaporizhya National Medical University
Petro I. Yagodynets´
Chernivtsi National University
Published June 29, 2020
Keywords
  • conducting polymer composites,
  • rhenium,
  • assisted polymerization,
  • electrochemical oscillations,
  • stable steady-state
How to Cite
(1)
Tkach, V. V.; Kushnir, M. V.; Storoshchuk, N. M.; Parchenko, V. V.; Aksyonova, I. I.; Odyntsova, V. M.; Luganska, O. V.; Yagodynets´P. I. The Theoretical Description of Cathodic Deposition of New Conducting Polymer Composite, Assisted by a Perrhenate of a Novel Triazolic Derivative. Orbital: Electron. J. Chem. 2020, 12, 34-38.

Abstract

The theoretical description of a new sandwich-like rhenium-based polymer composite cathodic electrodeposition has been given. The cathodic process is realized by perrhenate-ion electrochemical reduction to rhenium (IV) oxide, acting as an in situ formed oxidant for 3,4-dimethoxypyrrole polymerization.  It is shown that the polymer deposition in this system is realized by more efficient manner than during the direct electropolymerization. The polymer composite has to have a well-developed morphology and enhanced conductivity by sandwich-like structure. The oscillatory behavior, in this case, is also possible, being caused by the DEL influences on both electrochemical and chemical stages of the process.

DOI: http://dx.doi.org/10.17807/orbital.v12i2.1193