Orbital - Vol. 10 No. 2 - January-March 2018
SHORT COMMUNICATIONS

A Microwave Step for the Synthesis of 4,5-Dicyanopyridazine: A Great Forerunner to Phthalocyanines

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  • Charles Biral Silva,
  • Hueder Paulo Moisés de Oliveira,
  • Anderson Orzari Ribeiro
Charles Biral Silva
Universidade Federal do ABC – UFABC, Centro de Ciências Naturais e Humanas, Santo André, São Paulo, Brazil
Hueder Paulo Moisés de Oliveira
Universidade Federal do ABC – UFABC, Centro de Ciências Naturais e Humanas, Santo André, São Paulo, Brazil
Anderson Orzari Ribeiro
Universidade Federal do ABC – UFABC, Centro de Ciências Naturais e Humanas, Santo André, São Paulo, Brazil
Published April 1, 2018
Keywords
  • 4,5-dicyanopyridazine,
  • microwave,
  • pyridazine,
  • phthalonitriles
How to Cite
(1)
Silva, C. B.; de Oliveira, H. P. M.; Ribeiro, A. O. A Microwave Step for the Synthesis of 4,5-Dicyanopyridazine: A Great Forerunner to Phthalocyanines. Orbital: Electron. J. Chem. 2018, 10, 153-155.

Copyright (c) 2018 Orbital: The Electronic Journal of Chemistry

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Abstract

4,5-Dicyanopyridazine (DCP) shows unexpected reactivity with dienophiles via Hetero Diels-Alder. Reactions involving this compound and alkynes or enamines was already described, open possibilities to synthesize precursors for important macromolecules, like phthalonitriles used in phthalocyanines synthesis. Herein, we present a microwave synthetic step in the DCP synthetic route in order to minimize the time to synthesize this compound.

DOI: http://dx.doi.org/10.17807/orbital.v10i2.1133

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